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scgnientation concepts 4 j . Go, 7 2 - 5 3 , '43 6, 160-1 strike-level .igrccnients 1-)1~81 seven principle drrvers 1- 14,

8. Turn off the 2D layer. 9. Save your drawing. It should look like Figure 24-17. If you want, add a polysolid over the front door and rotate the front door to open it. You should also change the DELOBJ system variable back to its original value.

but there is nothing that would prevent the same style from being used for very coarse-granularity, stateless component instances .

The reaction is initiated in step 2 and propagated by steps 3 and 4 Analyze each of the steps of the Hunsdiecker reaction in terms of simple orbital interaction theory (a) Using a two-orbital interaction diagram, show the interaction which results in the formation of the bromoxy acid, 7, and displacement of bromide ion in step 1 (b) Use an appropriate orbital interaction diagram to describe the O Br bond of 7, which ruptures upon heating in step 2 Why is it feasible that this is the weakest bond in this compound (c) Show the electronic structure of the acyloxy free radical, 8, which is produced in step 2 Is it a s or p radical Hint: You may wish to construct the MOs of 8 from the interaction of two monocoordinated oxygen atoms, bearing in mind the local symmetry of the carboxylate group.

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(d) Use your bonding description from part (b) to explain why the alkyl radical should attack at the Br atom of 7 and not at some other site in step 4 Answer (a) This is a simple nucleophilic substitution on Br2 The Br Br s-type interaction is very weak, and as a consequence, the LUMO sBrBr is low in energy The interaction is of the two-electron, two-orbital type, the other orbital being the HOMO of the carboxylate group, the out-of-phase combination of the in-plane nonbonded orbitals of the oxygen atoms [p2 will be a little lower; see part (c)] (b) The s bond of the bromoxy acid is very weak because of the poor intrinsic interaction between a 2p orbital and a 4p orbital (c) The interaction diagram for the carboxylate group is shown in Figure B3.

At this point, you can do all of the types of searches that you did earlier with Oracle Text. Here is one example:

Because the in-plane p orbitals ps overlap more strongly than the out-of-plane orbitals pp , the HOMO of the carboxylate anion will be a s orbital, and the neutral carboxylate free radical is predicted to be a s radical..

Nov 8 18:00 4Suite Mar 23 2005 a2ps.cfg Mar 23 2005 a2ps-site.cfg Mar 16 2005 acpi Nov 8 16:49 adjtime Mar 3 2005 alchemist

This option allows you to specify how many frames you want to be created between the frames you are tweening. This is determined by how long your frame rate is and the complexity of the difference in the frames you want to tween.

Tip As soon as you have a separate layer for the hidden portion of the model, you can modify that layer s color and/or linetype to show the hidden lines in a contrasting color or linetype. Flatten is a program that flattens everything except blocks from 3D to 2D. You can find it in \Software\Chap24\Flatten.

FIGURE 9.36 Geometry of a dual-band, circularly polarized, stacked elliptic microstrip antenna. (From Ref. 12, C 2000 John Wiley & Sons, Inc.)

Models Model 1 CurbWeight MaxGrossWeight FuelType FuelCapacity MPG 1 FuelTypes FuelType LicenserRequired Model State * Class

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